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The main purpose of this article to present a comprehensive review of the application of the Structural Equation Modelling (SEM) in the assessment of sustainable and green supply chain management (SCM). In this paper, we systematically identified, reviewed, and categorized the selected papers in various key perspectives, including application area, research problem and study purpose and gap, type of method and technique, name of variables, name and country of authors, related theory, unit of analysis, publication year, number of hypotheses, number of sample and scope, respondents, measure validation, data collection method, and finally, findings and results. The findings of this review study demonstrated that previous works have used the SEM in the field of green SCM. In addition, it appears the manufacturing sector had the highest rank among other sectors. Results report the majority of published papers …