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Borophene, a 2D allotrope of boron and the lightest elemental Dirac material, is the latest very promising 2D material owing to its unique structural and electronic characteristics of the X₃ and β₁₂ phases. The high atomic density on ridgelines of the β₁₂ phase of borophene provides a substantial orbital overlap, which leads to an excellent electron density in the conduction level and thus to a highly metallic behavior. These unique structural characteristics and electronic properties of borophene attract significant scientific interest. Herein, approaches for crystal growth/synthesis of these unique nanostructures and their potential technological applications are discussed. Various substrate‐supported ultrahigh‐vacuum growth techniques for borophene, such as molecular beam epitaxy, atomic layer deposition, and chemical vapor deposition, along with their challenges, are also summarized. The sonochemical …