作者
Jian Xu, Zeshuo Meng, Zeyu Hao, Xucong Sun, Haoshan Nan, Hongxu Liu, Yanan Wang, Wei Shi, Hongwei Tian, Xiaoying Hu
发表日期
2022/3/1
期刊
Journal of Colloid and Interface Science
卷号
609
页码范围
878-889
出版商
Academic Press
简介
Bi2O3 is an outstanding electrode material due to its high theoretical specific capacity. Hence, the synthesis of δ-Bi2O3 materials with high oxygen-vacancy contents could improve their electrochemical performances but causes easy conversion to α-Bi2O3 with low oxygen-vacancy contents, leading to poor cycling stability and limited practical applications. To overcome these problems, an effective strategy for constructing high oxygen vacancies α-Bi2O3 on activated carbon fiber paper (ACFP) is developed in this study. To this end, ACFP/Bi(OH)3 is first synthesized by the solvothermal method and then converted to ACFP/α-Bi2O3 by in situ electrochemical activation. The proposed innovative electrochemical method quickly and easily introduces oxygen vacancies while preserving the three-dimensional structure, thereby promoting the charge transfer and ions diffusion in ACFP/α-Bi2O3. Consequently, the specific …
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