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In the Internet of Things (IoT), a lot of constrained devices are interconnected. The data collected from those devices can be the target of cyberattacks. In this paper, a lightweight cryptosystem that can be efficiently implemented in highly constrained IOT devices is proposed. The algorithm is mainly based on Advanced Encryption Standard (AES) and a new chaotic S-box. Since its adoption by the IEEE 802.15.4 protocol, AES in embedded platforms have been increasingly used. The main cryptographic properties of the generated S-box have been validated. The randomness of the generated S-box has been confirmed by the NIST tests. Experimental results and security analysis demonstrated that the cryptosystem can, on the one hand, reach good encryption results and respects the limitation of the sensor’s resources, on the other hand. So the proposed solution could be reliably applied in image encryption and secure communication between networked smart objects.