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The crystallization processes of two anhydrous salts (NaCl and Na₂SO₄) and one hydrated (sodium sulfate) salt in the pore space of a natural building stone, Savonnières limestone, are studied. We imaged the salt solution distribution before and after crystallization and the solid crystal distribution in between repeated crystallization cycles using synchrotron X-ray microtomography. This technique proves to be very useful to study salt crystallization processes at the pore scale. The use of simultaneous phase-and-amplitude retrieval during X-ray tomographic reconstruction allows a clear segmentation of sodium sulfate solution and hydrated sodium sulfate crystals without the need for a dopant. Salt crystals can precipitate under unconfined as well as confined conditions in the multiple pore systems of Savonnières limestone, depending on their interconnection. Salt solution and salt crystals are located in …