查看文章

Ammonia has been recently recognized as a promising carbon-free fuel to help decarbone both the power and industrial heating sectors. However, fuel slip during ammonia combustion is of high concern because of the high toxicity of the chemical, motivating the development of sensitive sensors for real-time monitoring of ammonia emission in combustion flue gases. In this work, a near-infrared absorption spectroscopic sensor was developed for trace ammonia (NH 3) measurements in high-humidity flue gas environments with water vapor (H 2 O) mole fractions up to 40%. The focus on high humidity is motivated by the facct that ammonia combustion generally leads to flues gases with notably higher water vapor concentations as compared to conventional hydrocarbons. The sensor used a distributed feedback laser to target the NH 3 absorption line near 6612.73 cm− 1. Proof-of-concept tests were conducted in a …