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The binary iron–chromium alloy embrittles in the temperature range of 280–500°C limiting its applications to temperatures below 280°C. The embrittlement is caused by the decomposition of the alloy to chromium-rich phase, α′ and iron-rich phase, α. This phenomenon is termed 475°C embrittlement as the rate of embrittlement is highest at 475°C. Primarily the investigations on 475°C embrittlement were confined to binary iron–chromium alloys and ferritic stainless steels. Duplex stainless steel grades contain varying proportions of ferrite and austenite in the microstructure and the ferritic phase is highly alloyed. Moreover, this grade of steel has several variants depending on the alloy composition and processing route. This modifies the precipitation behaviour and the resulting change in mechanical properties in duplex stainless steels when embrittled at 475°C as compared to binary iron chromium systems. The …