作者
Kevin D Belfield, Alma R Morales, Bong-Soo Kang, Joel M Hales, David J Hagan, Eric W Van Stryland, Victor M Chapela, Judith Percino
发表日期
2004/11/16
期刊
Chemistry of materials
卷号
16
期号
23
页码范围
4634-4641
出版商
American Chemical Society
简介
The synthesis of a series of four new compounds containing fluorenyl chromophores is presented, along with the results of spectroscopic and photochemical studies aimed at understanding the two-photon absorption properties and energetics of their electronically excited states. The molecular structures of the compounds were systematically varied to allow comparison of molecules possessing high and low molecular symmetry, short and long alkyl chains, and a fluorenyl conjugated π-system. Solvent-dependent absorption and emission were investigated along with π-conjugation length. Preliminary measurements of two-photon absorption (2PA) using a two-photon fluorescence method indicate that these chromophores exhibit high two-photon absorptivity. A symmetrical molecule (3), possessing a relatively large π-conjugated system, flanked on either side by electron-withdrawing groups (benzothiazole …
引用总数
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Synthesis, characterization, and optical properties of new two-photon-absorbing fluorene derivatives
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