作者
Izaro Laresgoiti, Stefan Käbitz, Madeleine Ecker, Dirk Uwe Sauer
发表日期
2015/12/30
期刊
Journal of Power Sources
卷号
300
页码范围
112-122
出版商
Elsevier
简介
During cycling, mechanical stresses can occur in the composite electrode, inside the active material, but also in the solid electrolyte interphase layer. A mechanical model is proposed based on a system made of a spherical graphite particle surrounded by the solid electrolyte interphase layer. During lithium intercalation or de-intercalation, stresses in the graphite are produced, governed by the diffusion induced stress phenomena and in the solid electrolyte interphase, driven by the graphite expansion. The stresses in both materials were simulated and a sensitivity analysis was performed to clarify the influence of principal parameters on both processes. Finally, assuming that the solid electrolyte interphase is the weakest material and therefore more prone to fracture than graphite, the experimental capacity fade during cycling was modeled based on its break and repair effect rather than on the fracture of the active …
引用总数
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