作者
Chunfang Cai, Richard H Worden, Simon H Bottrell, Lansheng Wang, Chanchun Yang
发表日期
2003/12/15
期刊
Chemical Geology
卷号
202
期号
1-2
页码范围
39-57
出版商
Elsevier
简介
The Sichuan Basin in China is a sour petroleum province. In order to assess the origin of H2S and other sulphur compounds as well as the cause of petroleum alteration, data on H2S, thiophene and thiol concentrations and gas stable isotopes (δ34S and δ13C) have been collected for predominantly gas phase petroleum samples from Jurassic, Triassic, Permian and Upper Proterozoic (Sinian) reservoirs. The highest H2S concentrations (up to 32%) are found in Lower Triassic, anhydrite-rich carbonate reservoirs in the Wolonghe Field where the temperature has reached >130 °C. δ34S values of the H2S in the Wolonghe Triassic reservoirs range from +22 to +31‰ and are close to those of Triassic evaporitic sulphate from South China. All the evidence suggests that the H2S was generated by thermochemical sulphate reduction (TSR) locally within Triassic reservoirs. In the Triassic Wolonghe Field, both methane …
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