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Pythagorean fuzzy set (PFS) whose main feature is that the square sum of the membership degree and the non‐membership degree is equal to or less than one, is a powerful tool to express fuzziness and uncertainty. The aim of this paper is to investigate aggregation operators of Pythagorean fuzzy numbers (PFNs) based on Frank t‐conorm and t‐norm. We first extend the Frank t‐conorm and t‐norm to Pythagorean fuzzy environments and develop several new operational laws of PFNs, based on which we propose two new Pythagorean fuzzy aggregation operators, such as Pythagorean fuzzy Choquet–Frank averaging operator (PFCFA) and Pythagorean fuzzy Choquet–Frank geometric operator (PFCFG). Moreover, some desirable properties and special cases of the operators are also investigated and discussed. Then, a novel approach to multi‐attribute decision making (MADM) in Pythagorean fuzzy context is …