作者
R Hollerweger, H Riedl, J Paulitsch, M Arndt, R Rachbauer, P Polcik, Sophie Primig, PH Mayrhofer
发表日期
2014/10/25
期刊
Surface and Coatings Technology
卷号
257
页码范围
78-86
出版商
Elsevier
简介
Alloying Ti–Al–N coatings with Ta has proven to enhance their hardness, thermal stability, and oxidation resistance. However, especially for arc-evaporated Ti–Al–Ta–N coatings only limited information on the detailed influence of the elements on various properties is available. Therefore, we have developed arc-evaporated Ti1−x−yAlxTayN coatings with various Al (x = 0.50–0.65) and Ta (y = 0.00–0.15) contents. While the thermal stability of our coatings during annealing in inert He atmosphere increases with increasing Ta content, best results are obtained for specific Ta–Al ratios during oxidation. Single phase cubic Ti0.32Al0.60Ta0.08N yields a mass-gain of only ~ 5% after 5 h at 950 °C in synthetic air, whereas Ti0.35Al0.65N is completely oxidized after 15 min. This is in part based on the suppressed anatase and direct rutile TiO2 formation at a defined Ta–Al content. Consequently, the anatase-to-rutile …
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