作者
Cheng Man, Chaofang Dong, Jianxiong Liang, Kui Xiao, Qiang Yu, Xiaogang Li
发表日期
2017/5/3
期刊
Analytical Letters
卷号
50
期号
7
页码范围
1091-1111
出版商
Taylor & Francis
简介
Electrochemistry methods were used to investigate the influence of pH on the passive film and corrosion behavior of ultrahigh strength AM355 stainless steel in chloride-containing media. Analysis of the Pourbaix diagram indicates that AM355 stainless steel exhibits higher corrosion resistance in natural and near-natural environments than that in acidic and alkaline conditions. Electrochemistry measurements and composition analysis of the passive film show that pitting potential increased due to the enhanced repassivation capacity of AM355 stainless steel with increasing pH. The mixed MnS/oxide inclusions are the main pitting sensitive locations under all conditions. Morphological observations and energy-dispersive spectroscopy showed that the influence of the gap between the martensitic laths is significant with increasing pH. The inclusions, element concentrations, and microstructures weaken the resistance …
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