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This study presents a novel method to identify optically deep water using purely spectral approaches. Optically deep waters, where the seabed is too deep for a bottom reflectance signal to be returned, is uninformative for seabed mapping. Furthermore, owing to the attenuation of light in the water column, submerged vegetation at deeper depths is easily confused with optically deep waters, thereby inducing misclassifications that reduce the accuracy of these seabed maps. While bathymetry data could mask out deeper areas, they are not always available or of sufficient spatial resolution for use. Without bathymetry data and based on the coastal aerosol blue green (1-2-3) bands of the Sentinel-2 imagery, this study investigates the use of band ratios and a false colour HSV transformation of both L1C and L2A images to separate optically deep and shallow waters across varying water quality over four tropical and temperate submerged sites: Tanzania, the Bahamas, the Caspian Sea (Kazakhstan) and the Wadden Sea (Denmark and Germany). Two supervised thresholds based on annotated reference data and an unsupervised Otsu threshold were applied. The band ratio group usually featured the best overall accuracies (OA), F1 scores and Matthews correlation coefficients, although the individual band combination might not perform consistently across different sites. Meanwhile, the saturation and hue band yielded close to best performance for the L1C and L2A images, featuring OA of up to 0.93 and 0.98, respectively, and a more consistent behaviour than the individual band ratios. Nonetheless, all these spectral methods are still susceptible to …