作者
Raziyeh Zandi Pak, Soheil Sobhan Ardakani
发表日期
2016/2/10
期刊
Iranian Journal of Toxicology
卷号
10
期号
2
页码范围
51-58
出版商
Iranian Journal of Toxicology
简介
Background: Among different pollutants released into the environment, dyes are considered as one of the most dangerous contaminants. In recent years, magnetic nanomaterials have attracted much attention for their dye removal capacity. The aim of this study was to explore the adsorption kinetics of an anionic dye (Reactive Orange 13 (RO)) by NiFe 2 O 4 nanoparticles (NiFe 2 O 4 NPs) under various conditions.
Methods: NiFe 2 O 4 nanoparticles (NiFe 2 O 4 NPs) were prepared and characterized by X-ray diffraction (XRD), transmission electronic microscopy (TEM), pH pzc and BET methods. The adsorption characteristics of the NiFe 2 O 4 NPs adsorbent were examined using Reactive Orange 13 as an adsorbate. The influences of parameters including pH, dose of adsorbent and contact time were investigated to find the optimum adsorption conditions.
Results: Decreasing solution pH and increasing contact time were favorable for improving adsorption efficiency. The kinetic and isotherm data of RO adsorption on NiFe 2 O 4 NPs were well fitted by pseudo-second-order and Langmuir models, respectively.
Conclusion: The maximal adsorption capacity of RO was 243.9 mg g-1 at 25◦ C and pH 3.0 and the adsorption of RO on the NiFe 2 O 4 NPs follows a monolayer coverage model. NiFe 2 O 4 NPs might be an effective and potential adsorbent for removing anionic dyes from aqueous solutions.
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