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This paper presents the novel designs of a concentric cylindrical thermoelectric generator (CCTEG) and an annular thermoelectric module (ATEM). The simulations are carried out to compare the performance of ATEM and the conventional square-shaped thermoelectric module (STEM). The heat pipe technology is introduced into the heat sink system in order to enhance the heat transfer in the radial direction of exhaust gas flow. A new index termed as the heat transfer filling factor f has been introduced which quantities the level of space utilisation for thermoelectric modules (TEMs). The correlation between the coolant flow rate and TEM performance is also carried out. Experimental work is also carried out to demonstrate the viability of using the heat pipes for heat transfer enhancement as well proving the viability of the design. The simulations indicate that the open circuit electric potential of the ATEM is 17% more …