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A new phenoxycyclotriphosphazene derivative ligand, 2-chloro -2-salicylideneimino-1,10-phenanthrolino-4,4,6,6-bis[spiro(2′,2″-dioksi-1′,1″-bifenil)]cyclotriphosp- hazane (CS-CP), has been synthesized from the reaction of 2,2-dichloro-4,4,6,6-bis[spiro(2′,2″-dioxybiphenyl)] cyclotriphosphazane and 5-salicylideneimino-1,10-phenanthroline and Ru(II) complex of this ligand has been prepared. The newly synthesized compounds have been verified by FTIR,¹H NMR, ³¹P NMR, UV-vis., mass, and fluorescence spectra, together with elemental and thermal analysis.