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Quantum key distribution (QKD) generates symmetric keys between two remote parties and guarantees the keys are not accessible to any third party. Wavelength-division multiplexing between QKD and classical optical communications by sharing the existing fiber-optics infrastructure is highly desired in order to reduce the cost of QKD applications. However, comparing to the light for classical transmission, quantum signals are very weak and easily affected by impairments from classical light, such as the spontaneous Raman-scattering effect. Here, by selecting an optimal wavelength of quantum signals, we significantly reduce the influence of the Raman-scattering effect. In addition, through coherent optical communication technology, we achieve high-speed classical data transmission with relatively low launch powers, thereby further reducing the impairments from classical light. As a result, we realize the …