作者
KY Pérez-Salcedo, IL Alonso-Lemus, P Quintana, CJ Mena-Durán, Romeli Barbosa, B Escobar
发表日期
2019/5/9
期刊
International Journal of Hydrogen Energy
卷号
44
期号
24
页码范围
12399-12408
出版商
Pergamon
简介
In this work, high surface area N-doped carbon synthesis from Sargassum spp. is reported as a low cost alternative for electrocatalysts production for the oxygen reduction reaction (ORR). First, Sargassum spp. was activated with potassium hydroxide (SKPH) and then doped with hydrazine (SKPHD). As a result of the activation process, SKPH obtained a high surface area (2289 m2 g−1), 0.16% nitrogen and 2.63% sulfur content; it also showed four-electron-transfer mechanism when tested as electrocatalyst in alkaline medium. Besides, SKPHD presented 3.60% nitrogen content in the bulk and higher ORR activity (0.838 V onset potential vs. RHE and 4.59 mA cm−2 current density) very close to 20% Pt/C (5.25 mA cm−2). Results indicate that using seaweeds as a synthesis precursor is an alternative for the Sargassum spp. disposal in the Caribbean due to its high availability and efficiency towards ORR.
引用总数
201920202021202220232024449666
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KY Pérez-Salcedo, IL Alonso-Lemus, P Quintana… - International Journal of Hydrogen Energy, 2019