作者
Ahmet Sari, Mustafa Tuzen, Demirhan Citak, Mustafa Soylak
发表日期
2007/10/22
期刊
Journal of hazardous materials
卷号
149
期号
2
页码范围
283-291
出版商
Elsevier
简介
The adsorption of Pb(II) onto Turkish (Bandırma region) kaolinite clay was examined in aqueous solution with respect to the pH, adsorbent dosage, contact time, and temperature. The linear Langmuir and Freundlich models were applied to describe equilibrium isotherms and both models fitted well. The monolayer adsorption capacity was found as 31.75mg/g at pH 5 and 20°C. Dubinin–Radushkevich (D–R) isotherm model was also applied to the equilibrium data. The mean free energy of adsorption (13.78kJ/mol) indicated that the adsorption of Pb(II) onto kaolinite clay may be carried out via chemical ion-exchange mechanism. Thermodynamic parameters, free energy (ΔG°), enthalpy (ΔH°) and entropy (ΔS°) of adsorption were also calculated. These parameters showed that the adsorption of Pb(II) onto kaolinite clay was feasible, spontaneous and exothermic process in nature. Furthermore, the Lagergren-first …
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