作者
Ahmet Sarı, Mustafa Tuzen
发表日期
2008/9/15
期刊
Journal of hazardous materials
卷号
157
期号
2-3
页码范围
448-454
出版商
Elsevier
简介
The biosorption characteristics of Cd(II) ions using the red alga (Ceramium virgatum) were investigated. Experimental parameters affecting the biosorption process such as pH, contact time, biomass dosage and temperature were studied. Langmuir, Freundlich and Dubinin–Radushkevich (D–R) models were applied to describe the biosorption isotherms. The biosorption capacity of C. virgatum biomass for Cd(II) ions was found to be 39.7mg/g. From the D–R isotherm model, the mean free energy was calculated as 12.7kJ/mol, indicating that the biosorption of Cd(II) the metal ions was taken place by chemisorption. The calculated thermodynamic parameters (ΔG°, ΔH° and ΔS°) showed that the biosorption of Cd(II) ions onto C. virgatum was feasible, spontaneous and exothermic at 293–323K. Evaluation of experimental data in terms of biosorption kinetics showed that the biosorption of Cd(II) C. virgatum followed well …
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