作者
Jianming Zhang, Xin Jin, Pablo I Morales-Guzman, Xin Yu, Hong Liu, Hua Zhang, Luca Razzari, Jerome P Claverie
发表日期
2016/4/26
期刊
ACS nano
卷号
10
期号
4
页码范围
4496-4503
出版商
American Chemical Society
简介
Recently, surface plasmon resonance (SPR) effects have been widely used to construct photocatalysts which are active in the visible spectral region. Such plasmonic photocatalysts usually comprise a semiconductor material transparent in the visible range (such as TiO2) and plasmonic nano-objects (e.g., Au nanoparticles (Au NPs)). Specific SPRs, though, only partially cover the visible spectrum and feature weak light absorption. Here, we explore the unique role played by whispering gallery mode (WGM) resonances in the expression of the photocatalytic activity of plasmonic photocatalysts. Using numerical simulations, we demonstrate that, by solely exploiting a proper geometrical arrangement and WGM resonances in a TiO2 sphere, the plasmonic absorption can be extended over the entire visible range and can be increased by more than 40 times. Furthermore, the local electric field at the Au–TiO2 interface is …
引用总数
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