作者
Aditya Sadhanala, Felix Deschler, Tudor H Thomas, Siân E Dutton, Karl C Goedel, Fabian C Hanusch, May L Lai, Ullrich Steiner, Thomas Bein, Pablo Docampo, David Cahen, Richard H Friend
发表日期
2014/8/7
期刊
The Journal of Physical Chemistry Letters
卷号
5
期号
15
页码范围
2501-2505
出版商
American Chemical Society
简介
Organometallic lead-halide perovskite-based solar cells now approach 18% efficiency. Introducing a mixture of bromide and iodide in the halide composition allows tuning of the optical bandgap. We prepare mixed bromide–iodide lead perovskite films CH3NH3Pb(I1–xBrx)3 (0 ≤ x ≤ 1) by spin-coating from solution and obtain films with monotonically varying bandgaps across the full composition range. Photothermal deflection spectroscopy, photoluminescence, and X-ray diffraction show that following suitable fabrication protocols these mixed lead-halide perovskite films form a single phase. The optical absorption edge of the pure triiodide and tribromide perovskites is sharp with Urbach energies of 15 and 23 meV, respectively, and reaches a maximum of 90 meV for CH3NH3PbI1.2Br1.8. We demonstrate a bromide–iodide lead perovskite film (CH3NH3PbI1.2Br1.8) with an optical bandgap of 1.94 eV, which is …
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A Sadhanala, F Deschler, TH Thomas, SE Dutton… - The Journal of Physical Chemistry Letters, 2014