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A carbon-coated Na3V2(PO4)2F3 nanocomposite (NVPF@C) is successfully realized by a facile sol–gel method. Carbon-coated NVPF nanoparticles are dispersed inside the mesoporous carbon matrix, which can not only improve the electron/ion transfer among different nanoparticles, but also benefit the electrolyte wetting during cycling. As a result, the NVPF@C cathode demonstrates remarkable Na+ storage performance: a high reversible capacity of nearly 130 mA h g−1 over 50 cycles between 4.3 and 2.0 V; superior rate capability with specific capacities of nearly 74 and 57 mA h g−1 at high current densities of 15C (1.92 A g−1) and 30C (3.84 A g−1), respectively; long-term cycle life with capacity retentions of 70% and 50% over 1000 and 3000 cycles at 10C and 30C rates. Thanks to the manifested high energy and power densities, the NVPF@C nanocomposite is suggested as a promising cathode material …