作者
Chang Hwan Kim, Gongshin Qi, Kevin Dahlberg, Wei Li
发表日期
2010/3/26
期刊
Science
卷号
327
期号
5973
页码范围
1624-1627
出版商
American Association for the Advancement of Science
简介
The high cost and poor thermal durability of current lean nitrogen oxides (NOx) aftertreatment catalysts are two of the major barriers to widespread adoption of highly fuel-efficient diesel engines. We demonstrated the use of strontium-doped perovskite oxides as efficient platinum substitutes in diesel oxidation (DOC) and lean NOx trap (LNT) catalysts. The lanthanum-based perovskite catalysts coated on monolith substrates showed excellent activities for the NO oxidation reaction, a critical step that demands heavy usage of platinum in a current diesel aftertreatment system. Under realistic conditions, La1-xSrxCoO3 catalysts achieved higher NO-to-NO2 conversions than a commercial platinum-based DOC catalyst. Similarly, a La0.9Sr0.1MnO3-based LNT catalyst achieved NOx reduction performance comparable to that of a commercial platinum-based counterpart. The results show promise for a considerably lower …
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