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Higher-order inference about a scalar parameter in the presence of nuisance parameters can be achieved by bootstrapping, in circumstances where the parameter of interest is a component of the canonical parameter in a full exponential family. The optimal test, which is approximated, is a conditional one based on conditioning on the sufficient statistic for the nuisance parameter. A bootstrap procedure that ignores the conditioning is shown to have desirable conditional properties in providing third-order relative accuracy in approximation of p-values associated with the optimal test, in both continuous and discrete models. The bootstrap approach is equivalent to third-order analytical approaches, and is demonstrated in a number of examples to give very accurate approximations even for very small sample sizes.