作者
Y Yuan, Y Wu, X Tong, H Zhang, H Wang, XJ Liu, L Ma, HL Suo, ZP Lu
发表日期
2017/2/15
期刊
Acta Materialia
卷号
125
页码范围
481-489
出版商
Pergamon
简介
In this paper, we report the development of rare-earth high-entropy alloys (RE-HEA) with multiple principle elements randomly distributed on a single hexagonal close-packed (HCP) lattice. Our work demonstrated that it is the entropy, rather than other atomic factors such as enthalpy, atomic size and electronegativity, that dictates phase formation in the current rare-earth alloy system. The high configuration entropy stabilized the crystalline structure from phase transformation during cooling, whereas a second-order magnetic phase transition occurred at its Neel temperature. The quinary RE-HEA exhibited a small magnetic hysteresis and the largest refrigerant capacity (about 627 J kg−1 at the 5 T magnetic field) reported to date, along with respectable mechanical properties. Our analysis indicates that the strong chemical disorder resulted from the high configuration entropy makes magnetic ordering in the HEA …
引用总数
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Y Yuan, Y Wu, X Tong, H Zhang, H Wang, XJ Liu, L Ma… - Acta Materialia, 2017