作者
Nicola Gasparini, Michael Salvador, Thomas Heumueller, Moses Richter, Andrej Classen, Shreetu Shrestha, Gebhard J Matt, Sarah Holliday, Sebastian Strohm, Hans‐Joachim Egelhaaf, Andrew Wadsworth, Derya Baran, Iain McCulloch, Christoph J Brabec
发表日期
2017/11
期刊
Advanced Energy Materials
卷号
7
期号
22
页码范围
1701561
简介
Organic semiconductors are in general known to have an inherently lower charge carrier mobility compared to their inorganic counterparts. Bimolecular recombination of holes and electrons is an important loss mechanism and can often be described by the Langevin recombination model. Here, the device physics of bulk heterojunction solar cells based on a nonfullerene acceptor (IDTBR) in combination with poly(3‐hexylthiophene) (P3HT) are elucidated, showing an unprecedentedly low bimolecular recombination rate. The high fill factor observed (above 65%) is attributed to non‐Langevin behavior with a Langevin prefactor (β/βL) of 1.9 × 10−4. The absence of parasitic recombination and high charge carrier lifetimes in P3HT:IDTBR solar cells inform an almost ideal bimolecular recombination behavior. This exceptional recombination behavior is explored to fabricate devices with layer thicknesses up to 450 nm …
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