作者
César Omar Ramírez Quiroz, Yilei Shen, Michael Salvador, Karen Forberich, Nadine Schrenker, George D Spyropoulos, Thomas Heumüller, Benjamin Wilkinson, Thomas Kirchartz, Erdmann Spiecker, Pierre J Verlinden, Xueling Zhang, Martin A Green, Anita Ho-Baillie, Christoph J Brabec
发表日期
2018/2/20
期刊
Journal of Materials Chemistry A
卷号
6
期号
8
页码范围
3583-3592
出版商
The Royal Society of Chemistry
简介
The unprecedented rise in efficiency of perovskite-based photovoltaics has sparked interest in semi-transparent devices, particularly for tandem structures. Despite promising reports regarding efficiency and reduced parasitic absorption, many devices still rely on processes from the gas phase, compromising both applicability and cost factors. Here, we report all-solution perovskite solar cells with improved infrared transparency ideally suited as top-cells for efficient multi-junction device configurations. We demonstrate the functionality of copper(I) thiocyanate as antireflective layer and as selective contact between the transparent conductive oxide and the perovskite. This concept allows us to fabricate an opaque device with steady state efficiency as high as 20.1%. By employing silver nanowires with robust environmental stability as the bottom electrode, we demonstrate different regimes of device performance that …
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