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A hydrochemical analysis of groundwater (GW) was conducted to investigate the factors controlling GW fluoride (F) in a large irrigation plain in the Yellow River Basin, Guanzhong Plain, China. Area-dependent variations in F were observed in the study region. The F concentrations of 93% of samples on the south bank of the Weihe River and the western part of the Qishui River were <1 mg L⁻¹, whereas those of 73% of GW samples for the eastern part of the Qishui River exceeded the national limit. A forward model based on mass budget equations identified carbonate weathering as the dominant factor regulating hydrochemistry in low-F GW, whereas the factors in the high-F zone were evaporate dissolution and evaporation. The high-F GW displayed a distinctive major ion chemistry, which could be attributed to a high pH, low Ca²⁺, and high HCO₃⁻ and Na⁺ concentrations. An analysis of the correlation between F …