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Sb₂Se₃ is a promising absorber material for photovoltaic cells because of its optimum band gap, strong optical absorption, simple phase and composition, and earth-abundant and nontoxic constituents. However, this material is rarely explored for photovoltaic application. Here we report Sb₂Se₃ solar cells fabricated from thermal evaporation. The rationale to choose thermal evaporation for Sb₂Se₃ film deposition was first discussed, followed by detailed characterization of Sb₂Se₃ film deposited onto FTO with different substrate temperatures. We then studied the optical absorption, photosensitivity, and band position of Sb₂Se₃ film, and finally a prototype photovoltaic device FTO/Sb₂Se₃/CdS/ZnO/ZnO:Al/Au was constructed, achieving an encouraging 2.1% solar conversion efficiency.