Dynamics of. alpha.-CH deprotonation and. alpha.-desilylation reactions of tertiary amine cation radicals X Zhang, SR Yeh, S Hong, M Freccero, A Albini, DE Falvey, PS Mariano Journal of the American Chemical Society 116 (10), 4211-4220, 1994 | 238 | 1994 |
Ab initio characterization of phenylnitrenium and phenylcarbene: remarkably different properties for isoelectronic species CJ Cramer, FJ Dulles, DE Falvey Journal of the American Chemical Society 116 (21), 9787-9788, 1994 | 167 | 1994 |
Dynamics of anilinium radical α-heterolytic fragmentation processes. Electrofugal group, substituent, and medium effects on desilylation, decarboxylation, and retro-aldol … Z Su, PS Mariano, DE Falvey, UC Yoon, SW Oh Journal of the American Chemical Society 120 (41), 10676-10686, 1998 | 157 | 1998 |
Model studies of DNA photorepair: Reduction potentials of thymine and cytosine cyclobutane dimers measured by fluorescence quenching MP Scannell, DJ Fenick, SR Yeh, DE Falvey Journal of the American Chemical Society 119 (8), 1971-1977, 1997 | 115 | 1997 |
Protecting groups that can be removed through photochemical electron transfer: Mechanistic and product studies on photosensitized release of carboxylates from phenacyl esters A Banerjee, DE Falvey The Journal of Organic Chemistry 62 (18), 6245-6251, 1997 | 112 | 1997 |
In vitro studies on the photobiological properties of aloe emodin and aloin A WG Wamer, P Vath, DE Falvey Free Radical Biology and Medicine 34 (2), 233-242, 2003 | 108 | 2003 |
Photochemical oxidation of water by 2-methyl-1, 4-benzoquinone: Evidence against the formation of free hydroxyl radical A Pochon, PP Vaughan, D Gan, P Vath, NV Blough, DE Falvey The Journal of Physical Chemistry A 106 (12), 2889-2894, 2002 | 99 | 2002 |
Photoremovable protecting groups based on electron transfer chemistry DE Falvey, C Sundararajan Photochemical & Photobiological Sciences 3, 831-838, 2004 | 97 | 2004 |
Direct photolysis of phenacyl protecting groups studied by laser flash photolysis: An excited state hydrogen atom abstraction pathway leads to formation of carboxylic acids and … A Banerjee, DE Falvey Journal of the American Chemical Society 120 (12), 2965-2966, 1998 | 95 | 1998 |
A simple route to fluids with photo-switchable viscosities based on a reversible transition between vesicles and wormlike micelles H Oh, AM Ketner, R Heymann, E Kesselman, D Danino, DE Falvey, ... Soft Matter 9 (20), 5025-5033, 2013 | 90 | 2013 |
Picosecond time scale dynamics of perester photodecomposition: evidence for an acyloxy radical intermediate in the photolysis of tert-butyl 9-methylfluorene-9-percarboxylate DE Falvey, GB Schuster Journal of the American Chemical Society 108 (23), 7419-7420, 1986 | 90 | 1986 |
Structures of Reactive Nitrenium Ions: Time-Resolved Infrared Laser Flash Photolysis and Computational Studies of Substituted N-Methyl-N-arylnitrenium Ions S Srivastava, PH Ruane, JP Toscano, MB Sullivan, CJ Cramer, ... Journal of the American Chemical Society 122 (34), 8271-8278, 2000 | 89 | 2000 |
A new photolabile protecting group for release of carboxylic acids by visible-light-induced direct and mediated electron transfer JB Borak, DE Falvey The Journal of Organic Chemistry 74 (10), 3894-3899, 2009 | 86 | 2009 |
Model studies of DNA photorepair: radical anion cleavage of thymine dimers probed by nanosecond laser spectroscopy SR Yeh, DE Falvey Journal of the American Chemical Society 113 (22), 8557-8558, 1991 | 86 | 1991 |
Photoinduced electron-transfer reactions in two room-temperature ionic liquids: 1-butyl-3-methylimidazolium hexafluorophosphate and 1-octyl-3-methylimidazolium hexafluorophosphate RC Vieira, DE Falvey The Journal of Physical Chemistry B 111 (18), 5023-5029, 2007 | 83 | 2007 |
Model studies of the (6-4) photoproduct DNA photolyase: Synthesis and photosensitized splitting of a thymine-5, 6-oxetane G Prakash, DE Falvey Journal Of The American Chemical Society 117 (45), 11375-11376, 1995 | 82 | 1995 |
Photogelling colloidal dispersions based on light-activated assembly of nanoparticles K Sun, R Kumar, DE Falvey, SR Raghavan Journal of the American Chemical Society 131 (20), 7135-7141, 2009 | 81 | 2009 |
Model studies of the (6− 4) photoproduct photolyase enzyme: Laser flash photolysis experiments confirm radical ion intermediates in the sensitized repair of thymine oxetane adducts A Joseph, G Prakash, DE Falvey Journal of the American Chemical Society 122 (45), 11219-11225, 2000 | 77 | 2000 |
Photogenerated arylnitrenium ions: reactions of N-tert-butyl (4-substituted 2-acetylphenyl) nitrenium ions with alcohols and water studied by laser flash photolysis RJ Robbins, LLN Yang, GB Anderson, DE Falvey Journal of the American Chemical Society 117 (24), 6544-6552, 1995 | 77 | 1995 |
Singlet− Triplet Splittings and 1, 2-Hydrogen Shift Barriers for Methylphenylborenide, Methylphenylcarbene, and Methylphenylnitrenium in the Gas Phase and Solution. What a … CJ Cramer, DG Truhlar, DE Falvey Journal of the American Chemical Society 119 (50), 12338-12342, 1997 | 76 | 1997 |