A synthetic high‐spin oxoiron (IV) complex: generation, spectroscopic characterization, and reactivity J England, M Martinho, ER Farquhar, JR Frisch, EL Bominaar, E Münck, ... Angewandte Chemie International Edition 48 (20), 3622-3626, 2009 | 319 | 2009 |
A family of starch-active polysaccharide monooxygenases VV Vu, WT Beeson, EA Span, ER Farquhar, MA Marletta Proceedings of the National Academy of Sciences 111 (38), 13822-13827, 2014 | 282 | 2014 |
The crystal structure of a high-spin oxoiron (IV) complex and characterization of its self-decay pathway J England, Y Guo, ER Farquhar, VG Young Jr, E Münck, L Que Jr Journal of the American Chemical Society 132 (25), 8635-8644, 2010 | 213 | 2010 |
Nonheme oxoiron (IV) complexes of pentadentate N5 ligands: spectroscopy, electrochemistry, and oxidative reactivity D Wang, K Ray, MJ Collins, ER Farquhar, JR Frisch, L Gómez, ... Chemical Science 4 (1), 282-291, 2013 | 181 | 2013 |
Swapping metals in Fe-and Mn-dependent dioxygenases: evidence for oxygen activation without a change in metal redox state JP Emerson, EG Kovaleva, ER Farquhar, JD Lipscomb, L Que Jr Proceedings of the National Academy of Sciences 105 (21), 7347-7352, 2008 | 150 | 2008 |
Lewis Acid Trapping of an Elusive Copper–Tosylnitrene Intermediate Using Scandium Triflate S Kundu, E Miceli, E Farquhar, FF Pfaff, U Kuhlmann, P Hildebrandt, ... Journal of the American Chemical Society 134 (36), 14710-14713, 2012 | 131 | 2012 |
A diiron (IV) complex that cleaves strong C–H and O–H bonds D Wang, ER Farquhar, A Stubna, E Münck, L Que Nature chemistry 1 (2), 145-150, 2009 | 107 | 2009 |
Crystal structure of Clostridium difficile toxin A NM Chumbler, SA Rutherford, Z Zhang, MA Farrow, JP Lisher, E Farquhar, ... Nature Microbiology 1, 15002, 2016 | 106 | 2016 |
A hyperactive cobalt-substituted extradiol-cleaving catechol dioxygenase AJ Fielding, EG Kovaleva, ER Farquhar, JD Lipscomb, L Que Jr JBIC Journal of Biological Inorganic Chemistry 16 (2), 341-355, 2011 | 93 | 2011 |
Electron paramagnetic resonance detection of intermediates in the enzymatic cycle of an extradiol dioxygenase WA Gunderson, AI Zatsman, JP Emerson, ER Farquhar, L Que Jr, ... Journal of the American Chemical Society 130 (44), 14465-14467, 2008 | 93 | 2008 |
Reduction of hexavalent chromium by the thermophilic methanogen Methanothermobacter thermautotrophicus R Singh, H Dong, D Liu, L Zhao, AR Marts, E Farquhar, DL Tierney, ... Geochimica et Cosmochimica Acta 148, 442-456, 2015 | 82 | 2015 |
Tuning the Reactivity of Terminal Nickel (III)–Oxygen Adducts for C–H Bond Activation P Pirovano, ER Farquhar, M Swart, AR McDonald Journal of the American Chemical Society 138 (43), 14362-14370, 2016 | 74 | 2016 |
Sulfur versus Iron Oxidation in an Iron− Thiolate Model Complex AR McDonald, MR Bukowski, ER Farquhar, TA Jackson, KD Koehntop, ... Journal of the American Chemical Society 132 (48), 17118-17129, 2010 | 70 | 2010 |
An ultra-stable oxoiron (iv) complex and its blue conjugate base J England, JO Bigelow, KM Van Heuvelen, ER Farquhar, M Martinho, ... Chemical Science 5 (3), 1204-1215, 2014 | 68 | 2014 |
Structure of RPE65 isomerase in a lipidic matrix reveals roles for phospholipids and iron in catalysis PD Kiser, ER Farquhar, W Shi, X Sui, MR Chance, K Palczewski Proceedings of the National Academy of Sciences 109 (41), E2747-E2756, 2012 | 67 | 2012 |
A Highly Reactive Oxoiron (IV) Complex Supported by a Bioinspired N3O Macrocyclic Ligand I Monte Pérez, X Engelmann, YM Lee, M Yoo, E Kumaran, ER Farquhar, ... Angewandte Chemie International Edition 56 (46), 14384-14388, 2017 | 62 | 2017 |
Elevated copper in the amyloid plaques and iron in the cortex are observed in mouse models of Alzheimer's disease that exhibit neurodegeneration MW Bourassa, AC Leskovjan, RV Tappero, ER Farquhar, CA Colton, ... Biomedical Spectroscopy and Imaging 2 (2), 129-139, 2013 | 61 | 2013 |
Trapping of a Highly Reactive Oxoiron (IV) Complex in the Catalytic Epoxidation of Olefins by Hydrogen Peroxide X Engelmann, DD Malik, T Corona, K Warm, ER Farquhar, M Swart, ... Angewandte Chemie International Edition 58 (12), 4012-4016, 2019 | 58 | 2019 |
Hydrogen Atom Transfer by a High-Valent Nickel-Chloride Complex P Mondal, P Pirovano, A Das, ER Farquhar, AR McDonald Journal of the American Chemical Society 140 (5), 1834-1841, 2018 | 56 | 2018 |
Characterization and Reactivity of a Terminal Nickel (III)–Oxygen Adduct P Pirovano, ER Farquhar, M Swart, AJ Fitzpatrick, GG Morgan, ... Chemistry-A European Journal 21 (9), 3785-3790, 2015 | 54 | 2015 |