Metallaboranes of the Early Transition Metals: Direct Synthesis and Characterization of [{(η5‐C5Me5) Ta} 2BnHm](n= 4, m= 10; n= 5, m= 11),[{(η5‐C5Me5) Ta} 2B5H10 (C6H4CH3 … SK Bose, K Geetharani, B Varghese, SM Mobin, S Ghosh Chemistry–A European Journal 14 (29), 9058-9064, 2008 | 94 | 2008 |
Direct Synthetic Route to Functionalized 1, 2‐Azaborinines H Braunschweig, K Geetharani, JOC Jimenez‐Halla, M Schaefer Angewandte Chemie International Edition 53 (13), 3500-3504, 2014 | 93 | 2014 |
Fine Tuning of Metallaborane Geometries: Chemistry of Metallaboranes of Early Transition Metals Derived from Metal Halides and Monoborane Reagents SK Bose, K Geetharani, V Ramkumar, SM Mobin, S Ghosh Chemistry–A European Journal 15 (48), 13483-13490, 2009 | 81 | 2009 |
Synthesis and Structural Characterization of New Divanada‐and Diniobaboranes Containing Chalcogen Atoms DK Roy, SK Bose, K Geetharani, KK Varma Chakrahari, SM Mobin, ... Chemistry–A European Journal 18 (32), 9983-9991, 2012 | 77 | 2012 |
Supraicosahedral polyhedra in metallaboranes: synthesis and structural characterization of 12-, 15-, and 16-vertex rhodaboranes DK Roy, B Mondal, P Shankhari, RS Anju, K Geetharani, SM Mobin, ... Inorganic Chemistry 52 (11), 6705-6712, 2013 | 75 | 2013 |
From metallaborane to borylene complexes: syntheses and structures of triply bridged ruthenium and tantalum borylene complexes K Geetharani, SK Bose, B Varghese, S Ghosh Chemistry–A European Journal 16 (37), 11357-11366, 2010 | 75 | 2010 |
Chemistry of Vanadaboranes: Synthesis, structures, and characterization of organovanadium sulfide clusters with disulfido linkage SK Bose, K Geetharani, V Ramkumar, B Varghese, S Ghosh Inorganic chemistry 49 (6), 2881-2888, 2010 | 71 | 2010 |
The Reactivities of Iminoboranes with Carbenes: BN Isosteres of Carbene–Alkyne Adducts H Braunschweig, WC Ewing, K Geetharani, M Schäfer Angewandte Chemie International Edition 54 (5), 1662-1665, 2015 | 69 | 2015 |
Cluster expansion reactions of group 6 and 8 metallaboranes using transition metal carbonyl compounds of groups 7–9 K Geetharani, SK Bose, S Sahoo, B Varghese, SM Mobin, S Ghosh Inorganic Chemistry 50 (12), 5824-5832, 2011 | 65 | 2011 |
A Family of Heterometallic Cubane‐Type Clusters with an exo‐Fe(CO)3 Fragment Anchored to the Cubane K Geetharani, SK Bose, S Sahoo, S Ghosh Angewandte Chemie International Edition 50 (17), 3908-3911, 2011 | 62 | 2011 |
A Mechanistic Study of the Utilization of arachno‐Diruthenaborane [(Cp*RuCO)2B2H6] as an Active Alkyne‐Cyclotrimerization Catalyst K Geetharani, S Tussupbayev, J Borowka, MC Holthausen, S Ghosh Chemistry–A European Journal 18 (27), 8482-8489, 2012 | 61 | 2012 |
Synthesis, characterization, and electronic structure of new type of heterometallic boride clusters SK Bose, K Geetharani, S Sahoo, KHK Reddy, B Varghese, ED Jemmis, ... Inorganic Chemistry 50 (19), 9414-9422, 2011 | 61 | 2011 |
C–H activation of arenes and heteroarenes by early transition metallaborane,[(Cp* Ta) 2 B 5 H 11](Cp*= η 5-C 5 Me 5) SK Bose, K Geetharani, S Ghosh Chemical Communications 47 (43), 11996-11998, 2011 | 61 | 2011 |
Efficient Synthesis of Aryl Boronates via Cobalt-Catalyzed Borylation of Aryl Chlorides and Bromides PK Verma, S Mandal, K Geetharani ACS Catalysis 8 (5), 4049-4054, 2018 | 60 | 2018 |
Condensed Tantalaborane Clusters: Synthesis and Structures of [(Cp*Ta)2B5H7{Fe(CO)3}2] and [(Cp*Ta)2B5H9{Fe(CO)3}4] SK Bose, K Geetharani, B Varghese, S Ghosh Inorganic chemistry 50 (6), 2445-2449, 2011 | 59 | 2011 |
Lewis acid catalysis: regioselective hydroboration of alkynes and alkenes promoted by scandium triflate S Mandal, PK Verma, K Geetharani Chemical Communications 54 (97), 13690-13693, 2018 | 56 | 2018 |
Synthesis and Characterization of Hypoelectronic Tantalaboranes: Comparison of the Geometric and Electronic Structures of [(Cp*TaX)2B5H11] (X = Cl, Br, and I) K Geetharani, BS Krishnamoorthy, S Kahlal, SM Mobin, JF Halet, S Ghosh Inorganic Chemistry 51 (19), 10176-10184, 2012 | 53 | 2012 |
Unusual Organic Chemistry of a Metallaborane Substrate: Formation of a Tantalaborane Complex with a Bridging Acyl Group (μ-η2) SK Bose, K Geetharani, B Varghese, S Ghosh Inorganic chemistry 49 (14), 6375-6377, 2010 | 52 | 2010 |
Synthesis of Functionalized 1,4-Azaborinines by the Cyclization of Di-tert-butyliminoborane and Alkynes M Schäfer, NA Beattie, K Geetharani, J Schäfer, WC Ewing, M Krahfuß, ... Journal of the American Chemical Society 138 (26), 8212-8220, 2016 | 48 | 2016 |
A fine tuning of metallaborane to bridged-boryl complex,[(Cp* Ru) 2 (μ-H)(μ-CO)(μ-Bcat)](cat= 1, 2-O 2 C 6 H 4; Cp*= η 5-C 5 Me 5) RS Anju, DK Roy, K Geetharani, B Mondal, B Varghese, S Ghosh Dalton Transactions 42 (36), 12828-12831, 2013 | 46 | 2013 |