A Bio-Inspired, Catalytic E → Z Isomerization of Activated Olefins JB Metternich, R Gilmour Journal of the American Chemical Society 137 (35), 11254-11257, 2015 | 337 | 2015 |
Fluorine conformational effects in organocatalysis: an emerging strategy for molecular design LE Zimmer, C Sparr, R Gilmour Angewandte Chemie International Edition 50 (50), 11860-11871, 2011 | 271 | 2011 |
Catalytic difluorination of olefins IG Molnar, R Gilmour Journal of the American Chemical Society 138 (15), 5004-5007, 2016 | 250 | 2016 |
One Photocatalyst, n Activation Modes Strategy for Cascade Catalysis: Emulating Coumarin Biosynthesis with (−)-Riboflavin JB Metternich, R Gilmour Journal of the American Chemical Society 138 (3), 1040-1045, 2016 | 248 | 2016 |
Advances in the E → Z Isomerization of Alkenes Using Small Molecule Photocatalysts T Nevesely, M Wienhold, JJ Molloy, R Gilmour Chemical reviews 122 (2), 2650-2694, 2021 | 240 | 2021 |
Positional and geometrical isomerisation of alkenes: the pinnacle of atom economy JJ Molloy, T Morack, R Gilmour Angewandte Chemie International Edition 58 (39), 13654-13664, 2019 | 199 | 2019 |
The Fluorine‐Iminium Ion Gauche Effect: Proof of Principle and Application to Asymmetric Organocatalysis C Sparr, WB Schweizer, HM Senn, R Gilmour Angewandte Chemie International Edition 48 (17), 3065-3068, 2009 | 183 | 2009 |
The Fluorine Gauche Effect: A Brief History C Thiehoff, YP Rey, R Gilmour Israel Journal of Chemistry 57 (1-2), 92-100, 2017 | 180 | 2017 |
Enantioselective, catalytic vicinal difluorination of alkenes F Scheidt, M Schäfer, JC Sarie, CG Daniliuc, JJ Molloy, R Gilmour Angewandte Chemie 130 (50), 16669-16673, 2018 | 144 | 2018 |
Photocatalytic E → Z Isomerization of Polarized Alkenes Inspired by the Visual Cycle: Mechanistic Dichotomy and Origin of Selectivity JB Metternich, DG Artiukhin, MC Holland, M von Bremen-Kühne, ... The Journal of Organic Chemistry 82 (19), 9955-9977, 2017 | 142 | 2017 |
Bioinspired Radical Stetter Reaction: Radical Umpolung Enabled by Ion‐Pair Photocatalysis T Morack, C Mück‐Lichtenfeld, R Gilmour Angewandte Chemie International Edition 58 (4), 1208-1212, 2019 | 141 | 2019 |
Boron-enabled geometric isomerization of alkenes via selective energy-transfer catalysis JJ Molloy, M Schäfer, M Wienhold, T Morack, CG Daniliuc, R Gilmour Science 369 (6501), 302-306, 2020 | 137 | 2020 |
Fluorine‐Directed Glycosylation C Bucher, R Gilmour Angewandte Chemie 46 (122), 8906-8910, 2010 | 136 | 2010 |
Contra‐Thermodynamic, Photocatalytic E→Z Isomerization of Styrenyl Boron Species: Vectors to Facilitate Exploration of Two‐Dimensional Chemical Space JJ Molloy, JB Metternich, CG Daniliuc, AJB Watson, R Gilmour Angewandte Chemie International Edition 57 (12), 3168-3172, 2018 | 135 | 2018 |
Total syntheses of amphidinolides B1, B4, G1, H1 and structure revision of amphidinolide H2 A Fürstner, LC Bouchez, L Morency, JA Funel, V Liepins, FH Porée, ... Chemistry–A European Journal 15 (16), 3983-4010, 2009 | 132 | 2009 |
Total syntheses of amphidinolide H and G A Fürstner, LC Bouchez, JA Funel, V Liepins, FH Porée, R Gilmour, ... Angewandte Chemie International Edition 46 (48), 9265-9270, 2007 | 129 | 2007 |
Deconstructing covalent organocatalysis MC Holland, R Gilmour Angewandte Chemie International Edition 54 (13), 3862-3871, 2015 | 124 | 2015 |
Stereochemical Models for Discussing Additions to α, β‐Unsaturated Aldehydes Organocatalyzed by Diarylprolinol or Imidazolidinone Derivatives–Is There an ‘(E)/(Z)‐Dilemma’? D Seebach, R Gilmour, U Grošelj, G Deniau, C Sparr, MO Ebert, AK Beck, ... Helvetica Chimica Acta 93 (4), 603-634, 2010 | 118 | 2010 |
Cyclopropyl iminium activation: reactivity umpolung in enantioselective organocatalytic reaction design C Sparr, R Gilmour Angewandte Chemie 36 (123), 8541-8545, 2011 | 117 | 2011 |
Stereochemical bias introduced during RNA synthesis modulates the activity of phosphorothioate siRNAs H Jahns, M Roos, J Imig, F Baumann, Y Wang, R Gilmour, J Hall Nature communications 6 (1), 6317, 2015 | 111 | 2015 |