Stereoselective and versatile preparation of tri-and tetrasubstituted allylic amine scaffolds under mild conditions W Guo, L Martínez-Rodríguez, R Kuniyil, E Martin, EC Escudero-Adán, ... Journal of the American Chemical Society 138 (36), 11970-11978, 2016 | 150 | 2016 |
Flow rhodaelectro-catalyzed alkyne annulations by versatile C–H activation: mechanistic support for rhodium (III/IV) WJ Kong, LH Finger, AM Messinis, R Kuniyil, JCA Oliveira, L Ackermann Journal of the American Chemical Society 141 (43), 17198-17206, 2019 | 144 | 2019 |
Late‐Stage Peptide Diversification through Cobalt‐Catalyzed C− H Activation: Sequential Multicatalysis for Stapled Peptides MM Lorion, N Kaplaneris, J Son, R Kuniyil, L Ackermann Angewandte Chemie 131 (6), 1698-1702, 2019 | 118 | 2019 |
A Domino Process toward Functionally Dense Quaternary Carbons through Pd-Catalyzed Decarboxylative C(sp3)–C(sp3) Bond Formation W Guo, R Kuniyil, JE Gómez, F Maseras, AW Kleij Journal of the American Chemical Society 140 (11), 3981-3987, 2018 | 105 | 2018 |
C− H oxygenation reactions enabled by dual catalysis with electrogenerated hypervalent iodine species and ruthenium complexes L Massignan, X Tan, TH Meyer, R Kuniyil, AM Messinis, L Ackermann Angewandte Chemie International Edition 59 (8), 3184-3189, 2020 | 86 | 2020 |
Photo‐Induced Ruthenium‐Catalyzed C− H Arylations at Ambient Temperature K Korvorapun, J Struwe, R Kuniyil, A Zangarelli, A Casnati, ... Angewandte Chemie International Edition 59 (41), 18103-18109, 2020 | 76 | 2020 |
Reactivity-controlling factors in carboxylate-assisted C–H activation under 4d and 3d transition metal catalysis T Rogge, JCA Oliveira, R Kuniyil, L Hu, L Ackermann ACS Catalysis 10 (18), 10551-10558, 2020 | 74 | 2020 |
Catalyst-free, direct electrochemical synthesis of annulated medium-sized lactams through C–C bond cleavage Z Xu, Z Huang, Y Li, R Kuniyil, C Zhang, L Ackermann, Z Ruan Green Chemistry 22 (4), 1099-1104, 2020 | 69 | 2020 |
Azaruthena (II)‐bicyclo [3.2. 0] heptadiene: Key Intermediate for Ruthenaelectro (II/III/I)‐catalyzed Alkyne Annulations L Yang, R Steinbock, A Scheremetjew, R Kuniyil, LH Finger, AM Messinis, ... Angewandte Chemie International Edition 59 (27), 11130-11135, 2020 | 68 | 2020 |
Manganese (I)‐Catalyzed C− H Activation/Diels–Alder/retro‐Diels–Alder Domino Alkyne Annulation featuring Transformable Pyridines C Zhu, R Kuniyil, L Ackermann Angewandte Chemie International Edition 58 (16), 5338-5342, 2019 | 67 | 2019 |
Late-Stage Diversification by Selectivity Switch in meta-C–H Activation: Evidence for Singlet Stabilization K Korvorapun, R Kuniyil, L Ackermann ACS Catalysis 10 (1), 435-440, 2019 | 63 | 2019 |
Peptide late-stage diversifications by rhodium-catalyzed tryptophan C7 amidation W Wang, J Wu, R Kuniyil, A Kopp, RN Lima, L Ackermann Chem 6 (12), 3428-3439, 2020 | 60 | 2020 |
Ruthenium-catalyzed C–H oxygenation of quinones by weak O-coordination for potent trypanocidal agents GG Dias, T Rogge, R Kuniyil, C Jacob, RFS Menna-Barreto, ... Chemical Communications 54 (91), 12840-12843, 2018 | 60 | 2018 |
Domino C–H Activation/Directing Group Migration/Alkyne Annulation: Unique Selectivity by d6-Cobalt(III) Catalysts C Zhu, R Kuniyil, BB Jei, L Ackermann ACS Catalysis 10 (7), 4444-4450, 2020 | 58 | 2020 |
N-heterocyclic carbene catalyzed asymmetric intermolecular stetter reaction: Origin of enantioselectivity and role of counterions R Kuniyil, RB Sunoj Organic letters 15 (19), 5040-5043, 2013 | 54 | 2013 |
Regioselective B (3, 4)–H arylation of o-carboranes by weak amide coordination at room temperature YF Liang, L Yang, BB Jei, R Kuniyil, L Ackermann Chemical Science 11 (39), 10764-10769, 2020 | 50 | 2020 |
Nickel-catalyzed dearomative Arylboration of indoles: regioselective synthesis of C2-and C3-Borylated indolines GL Trammel, R Kuniyil, PF Crook, P Liu, MK Brown Journal of the American Chemical Society 143 (40), 16502-16511, 2021 | 43 | 2021 |
Benzoate cyclometalation enables oxidative addition of haloarenes at a Ru (II) center M Simonetti, R Kuniyil, SA Macgregor, I Larrosa Journal of the American Chemical Society 140 (37), 11836-11847, 2018 | 34 | 2018 |
Electrocatalytic C–H phosphorylation through nickel (III/IV/II) catalysis SK Zhang, A Del Vecchio, R Kuniyil, AM Messinis, Z Lin, L Ackermann Chem 7 (5), 1379-1392, 2021 | 29 | 2021 |
π‐Extended Polyaromatic Hydrocarbons by Sustainable Alkyne Annulations through Double C− H/N− H Activation E Gońka, L Yang, R Steinbock, F Pesciaioli, R Kuniyil, L Ackermann Chemistry–A European Journal 25 (71), 16246-16250, 2019 | 24 | 2019 |