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Radio frequency (RF) based wireless power transfer provides an attractive solution to extend the lifetime of power-constrained wireless sensor networks. Through harvesting RF energy from surrounding environments or dedicated energy sources, low-power wireless devices can be self-sustaining and environment-friendly. These features make the RF energy harvesting wireless communication (RF-EHWC) technique attractive to a wide range of applications. The objective of this article is to investigate the latest research activities on the practical RF-EHWC design. The distribution of RF energy in the real environment, the hardware design of RF-EHWC devices and the practical issues in the implementation of RF-EHWC networks are discussed. At the end of this article, we introduce several interesting applications that exploit the RF-EHWC technology to provide smart healthcare services for animals, wirelessly charge the wearable devices, and implement 5G-assisted RF-EHWC.