Orthogonal frequency division multiplexing (OFDM) has been widely adopted for modern wireless standards and become a key enabling technology for cognitive radios. However, one of its main drawbacks is significant spectral leakage due to the accumulation of multiple siwc-shaped subcarriers. In this paper, we present a novel pulse shaping scheme for efficient spectral leakage suppression in OFDM based physical layer of IEEE 802.11af standard. With conventional pulse shaping filters such as a raised-cosine filter, vestigial symmetry can be used to reduce spectral leakage very effectively. However, these pulse shaping filters require long guard interval, i.e., cyclic prefix in an OFDM system, to avoid inter-symbol interference (ESI), resulting in a loss of spectral efficiency. The proposed pulse shaping method based on asymmetric pulse shaping achieves better spectral leakage suppression and decreases ISI caused by filtering as compared to conventional pulse shaping filters.