[HTML][HTML] A review of defect structure and chemistry in ceria and its solid solutions

R Schmitt, A Nenning, O Kraynis, R Korobko… - Chemical Society …, 2020 - pubs.rsc.org
Ceria and its solid solutions play a vital role in several industrial processes and devices.
These include solar energy-to-fuel conversion, solid oxide fuel and electrolyzer cells …

Ceria and its defect structure: new insights from a combined spectroscopic approach

A Filtschew, K Hofmann, C Hess - The Journal of Physical …, 2016 - ACS Publications
Ceria is an interesting component for a variety of catalytic and fuel cell applications. In the
study described here, ten different commercial ceria samples as well as synthesized ceria …

[HTML][HTML] Rare earth doped ceria: The complex connection between structure and properties

M Coduri, S Checchia, M Longhi, D Ceresoli… - Frontiers in …, 2018 - frontiersin.org
The need for high efficiency energy production, conversion, storage and transport is serving
as a robust guide for the development of new materials. Materials with physical-chemical …

Defect structure of Y-doped ceria on different length scales

M Coduri, M Scavini, M Allieta, M Brunelli… - Chemistry of …, 2013 - ACS Publications
An exhaustive structural investigation of a Y-doped ceria (Ce1–x Y x O2–x/2) system over
different length scales was performed by combining Rietveld and Pair Distribution Function …

Resolving a decade-long question of oxygen defects in Raman spectra of ceria-based catalysts at atomic level

Y Xu, F Wang, X Liu, Y Liu, M Luo, B Teng… - The Journal of …, 2019 - ACS Publications
Oxygen defects play a critically important role in redox reactions on ceria-based catalysts.
Raman spectroscopy is a key technique for the characterization of oxygen defects in ceria …

Oxygen vacancy ordering within anion-deficient ceria

S Hull, ST Norberg, I Ahmed, SG Eriksson… - Journal of Solid State …, 2009 - Elsevier
The structural properties of anion deficient ceria, CeO2− δ, have been studied as a function
of oxygen partial pressure, p (O2), over the range 0≥ log10p (O2)≥− 18.9 at 1273 (2) K …

Oxygen vacancy clusters on ceria: Decisive role of cerium electrons

C Zhang, A Michaelides, DA King, SJ Jenkins - Physical Review B …, 2009 - APS
Defects such as oxygen vacancies dominate the electronic and chemical properties of ceria.
However, fundamental understanding of such defects, especially clusters of vacancies, is …

Rare-earth-doped ceria systems and their performance as solid electrolytes: A puzzling tangle of structural issues at the average and local scale

C Artini - Inorganic Chemistry, 2018 - ACS Publications
Rare-earth (RE)-doped ceria systems, in particular when RE≡ Nd, Sm, or Gd, are well-
known to be characterized by high values of ionic conductivity in the intermediate …

Effects of Zr doping on stoichiometric and reduced ceria: A first-principles study

Z Yang, TK Woo, K Hermansson - The Journal of chemical physics, 2006 - pubs.aip.org
The Zr doping in Ce O 2 may change the reduction properties and therefore the redox
properties of Ce O 2⁠. Using first-principles density functional theory with the inclusion of on …

Ordering of oxygen vacancies and excess charge localization in bulk ceria: A study

GE Murgida, V Ferrari, MV Ganduglia-Pirovano… - Physical Review B, 2014 - APS
The importance of ceria (CeO 2) in many applications originates from the ease of oxygen
vacancy formation and healing. The ordering of vacancies and the whereabouts of the …