Surface Initiated Ring-Opening Polymerization as Tool for Grafting Polymers on Nanocelluloses

M Lalanne-Tisne - 2023 - lirias.kuleuven.be
This project is a collaboration between the group of Wim Thielemans, specialized in the
development of renewable materials using cellulose nanocrystals (CNCs), with the group of …

Cellulose nanocrystals modification by grafting from ring opening polymerization of a cyclic carbonate

M Lalanne-Tisné, S Eyley, J De Winter… - Carbohydrate …, 2022 - Elsevier
Surface modification of cellulose nanocrystals (CNC) by organocatalysed grafting from ring-
opening polymerization (ROP) of trimethylene carbonate was investigated. Organocatalysts …

Cellulose nanocrystals as initiator of ring-opening polymerization of ε-caprolactone: mathematical modeling and experimental verification

RP Rosa, FV Ferreira, DM dos Santos… - European Polymer …, 2022 - Elsevier
Cellulose nanocrystals (CNC) occupy a privileged position among the fillers for in situ
synthesis of polymer nanocomposites because such nanoparticles can be used as …

Mild and rapid surface initiated ring-opening polymerisation of trimethylene carbonate from cellulose

SA Pendergraph, G Klein, MKG Johansson… - RSC Advances, 2014 - pubs.rsc.org
Surface initiated ring-opening polymerisation (SI-ROP) of trimethylene carbonate (1, 3-
dioxane-2-one, TMC) from cellulose surfaces has been studied for the first time. Specifically …

Polymer grafting on nanocellulose

G Zhu, N Lin - Surface Modifications of Nanocellulose, 2024 - Elsevier
Grafting polymers onto cellulose nanocrystals (CNCs) has garnered significant interest in
both academia and industry. However, their surface hydroxyl groups can lead to irreversible …

Grafting Polymers from Cellulose Nanocrystals: Synthesis, Properties, and Applications

S Wohlhauser, G Delepierre, M Labet, G Morandi… - …, 2018 - ACS Publications
Over the past 10 years, the grafting of polymers from the surface of cellulose nanocrystals
(CNCs) has gained substantial interest in both academia and industry due to the rapidly …

Surface characteristics of cellulose nanoparticles grafted by surface-initiated ring-opening polymerization of ε-caprolactone

L Carlsson, T Ingverud, H Blomberg, A Carlmark… - Cellulose, 2015 - Springer
In this study, surface-initiated ring-opening polymerization has been employed for the
grafting of ε-caprolactone from cellulose nanoparticles, made by partial hydrolysis of …

Facile preparation route for nanostructured composites: surface-initiated ring-opening polymerization of ε-caprolactone from high-surface-area nanopaper

A Boujemaoui, L Carlsson, E Malmström… - … applied materials & …, 2012 - ACS Publications
In this work, highly porous nanopaper, ie, sheets of papers made from non-aggregated
nanofibrillated cellulose (NFC), have been surface-grafted with poly (ε-caprolactone)(PCL) …

Non‐Covalent Polymer Surface Modification of Cellulose Nanocrystals Using Block Copolymers

OL Torres‐Rocha, S Campbell… - Macromolecular …, 2022 - Wiley Online Library
Cellulose nanocrystals (CNC) possess desirable mechanical and optical properties that
make them a candidate in the development of the next generation of polymer‐based …

Surface-initiated controlled radical polymerization approach to enhance nanocomposite integration of cellulose nanofibrils

JRG Navarro, U Edlund - Biomacromolecules, 2017 - ACS Publications
A strategy is devised for the conversion of hydrophilic cellulose nanofibrils (CNFs) into
hydrophobic CNF that form a stable nanocomposite dispersion for functional reinforcement …