Preparation and Characterization of Cation-Substituted Na3SbS4 Solid Electrolytes

F Tsuji, N Masuzawa, A Sakuda… - ACS Applied Energy …, 2020 - ACS Publications
To realize all-solid-state sodium-ion batteries, the ionic conductivities and stabilities of solid
electrolytes must be improved. The sulfide Na3SbS4 electrolyte is known to show a high …

Effects of Substituting S with Cl on the Structural and Electrochemical Characteristics of Na3SbS4 Solid Electrolytes

H Gamo, NHH Phuc, H Muto… - ACS Applied Energy …, 2021 - ACS Publications
Herein, we report the synthesis of Na3–x SbS4–x Cl x (0≤ x≤ 0.1) solid electrolytes using a
liquid-phase method and describe their structural and electrochemical characteristics. A …

Tungsten and oxygen co-doped stable tetragonal phase Na3SbS4 with ultrahigh ionic conductivity for all-solid-state sodium batteries

W Weng, G Liu, Y Li, L Shen, X Yao - Applied Materials Today, 2022 - Elsevier
Abstract Development of sodium solid electrolytes with high ionic conductivity and good
interface stability towards Na metal plays a dominant role in achieving stable all-solid-state …

Synthesis of cubic Na3SbS4 solid electrolyte with enhanced ion transport for all-solid-state sodium-ion batteries

D Zhang, X Cao, D Xu, N Wang, C Yu, W Hu, X Yan… - Electrochimica …, 2018 - Elsevier
A comprehensive research coupling experiment and computation has been performed to
understand the phase transition of Na 3 SbS 4 and to synthesize cubic Na 3 SbS 4 (c-Na 3 …

Halogen Doping Mechanism and Interface Strengthening in the Na3SbS4 Electrolyte via Solid-State Synthesis

L Yu, J Yin, C Gao, C Lin, X Shen, S Dai… - ACS Applied Materials …, 2023 - ACS Publications
Good-performing sodium solid electrolytes (SSEs) are essential for constructing all-solid-
state sodium-ion batteries operating at ambient temperature. Sulfide solid electrolyte …

Multiphase Na3SbS4 with high ionic conductivity

H Gamo, NHH Phuc, R Matsuda, H Muto… - Materials Today …, 2019 - Elsevier
All-solid-state sodium-ion batteries using inorganic solid electrolytes containing abundant
sodium are promising candidates for large-scale energy storage applications. Solid …

High ionic conductivity and stable phase Na11. 5Sn2Sb0. 5Ti0. 5S12 for all-solid-state sodium batteries

W Weng, G Liu, L Shen, X Yao - Journal of Power Sources, 2021 - Elsevier
The quaternary antimony (Sb)-based sulfide sodium solid electrolyte Na 11 Sn 2 SbS 12
with good moisture stability is attractive for practical application in all-solid-state sodium …

Effects of I and W co-doping on the structural and electrochemical characteristics of Na3SbS4 glass-ceramic electrolytes

L Shu, B Liang, L Yu, C Lin, C Gao, X Shen, Y Liu… - Ceramics …, 2022 - Elsevier
Sodium-ion batteries are becoming a feasible choice for large-scale energy storage
because of their low cost and vast selection of cathode materials. Here we report the design …

Exceptionally high sodium ion conductivity and enhanced air stability in Na3SbS4 via germanium doping

L Yu, Q Jiao, B Liang, H Shan, C Lin, C Gao… - Journal of Alloys and …, 2022 - Elsevier
In addition to the widely used lithium-ion secondary batteries, more and more concerns have
been paid to solid-state batteries (SSBs) in the research on future-generation energy …

Excellent sodium ion conductivity and air stability of manganese-substituted Na 3 SbS 4 solid electrolytes

Z Gong, L Shu, J Yin, C Gao, Y Liu, X Zhou… - Journal of Materials …, 2023 - pubs.rsc.org
Solid electrolytes are promising candidates for addressing energy and environmental
problems due to their excellent electrical conductivity and extremely high safety. To date …