[3+ 2] cycloaddition reaction of metallacyclopropene with nitrosonium ion: isolation of aromatic metallaisoxazole
M Luo, Y Sui, X Lin, C Zhu, Z Yan, Y Ruan… - Chemical …, 2020 - pubs.rsc.org
The synthesis of metallaisoxazole by the [3+ 2] cycloaddition reaction of
metallacyclopropene with nitrosonium tetra-fluoroborate has been achieved under mild
conditions. Nuclear magnetic resonance spectra, X-ray crystallographic analysis, and
density functional theory calculations all suggest that the metallaisoxazole exhibits an
aromatic character.
metallacyclopropene with nitrosonium tetra-fluoroborate has been achieved under mild
conditions. Nuclear magnetic resonance spectra, X-ray crystallographic analysis, and
density functional theory calculations all suggest that the metallaisoxazole exhibits an
aromatic character.
The synthesis of metallaisoxazole by the [3+2] cycloaddition reaction of metallacyclopropene with nitrosonium tetra-fluoroborate has been achieved under mild conditions. Nuclear magnetic resonance spectra, X-ray crystallographic analysis, and density functional theory calculations all suggest that the metallaisoxazole exhibits an aromatic character.
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