we predict that it is inevitable that the time-reversal symmetry is broken spontaneously in a
superconducting Josephson junction formed by two superconductors with different pairing
symmetries dubbed as π/2-Josephson junction. While the leading conventional Josephson
coupling vanishes in such an π/2-Josephson junction, the second-order coupling from
tunneling always generates chiral superconductivity orders with broken time-reversal …