A Lewis acid-promoted reduction of acylsilanes to α-hydroxysilanes by diethylzinc
G Gao, XF Bai, F Li, LS Zheng, ZJ Zheng, GQ Lai… - Tetrahedron …, 2012 - Elsevier
We report here the first example of the reduction of acylsilanes to α-hydroxysilanes, in which
diethylzinc was used as a highly reactive agent in the presence of Ti (OiPr) 4 or other Lewis
acids. The reduction typically proceeds to give synthetically useful α-hydroxysilanes in good
yields.
diethylzinc was used as a highly reactive agent in the presence of Ti (OiPr) 4 or other Lewis
acids. The reduction typically proceeds to give synthetically useful α-hydroxysilanes in good
yields.
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