A nonelectrolyte local composition model and its application in the correlation of the mean activity coefficient of aqueous electrolyte solutions
A Haghtalab, SH Mazloumi - Fluid Phase Equilibria, 2009 - Elsevier
The local composition models have been widely used for the correlation of activity coefficient
of nonelectrolyte and electrolyte solutions. A new equation for the excess Gibbs energy
function is developed based on the local composition expression of Wilson and the random
reference state. This new function, the nonelectrolyte Wilson nonrandom factor (N-Wilson-
NRF) model, is presented in the form of a molecular framework so that it can be used for
both nonelectrolyte and electrolyte solutions. Without any particular assumptions for ionic …
of nonelectrolyte and electrolyte solutions. A new equation for the excess Gibbs energy
function is developed based on the local composition expression of Wilson and the random
reference state. This new function, the nonelectrolyte Wilson nonrandom factor (N-Wilson-
NRF) model, is presented in the form of a molecular framework so that it can be used for
both nonelectrolyte and electrolyte solutions. Without any particular assumptions for ionic …
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