A permanently porous van der Waals solid by using phosphonate monoester linkers in a metal organic framework

SS Iremonger, J Liang, R Vaidhyanathan… - Chemical …, 2011 - pubs.rsc.org
Chemical Communications, 2011pubs.rsc.org
A bis (phosphonatemonoester) is employed as a linker in a Zn (II) metal organic framework.
The complex is a layered structure pillared only by vdW interactions between alkyl groups.
Nonetheless, permanent pores are formed as confirmed by PXRD and gas sorption
analysis.
A bis(phosphonatemonoester) is employed as a linker in a Zn(II) metal organic framework. The complex is a layered structure pillared only by vdW interactions between alkyl groups. Nonetheless, permanent pores are formed as confirmed by PXRD and gas sorption analysis.
The Royal Society of Chemistry
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