A simple copper-catalyzed synthesis of tertiary acyclic amides
E Racine, F Monnier, JP Vors, M Taillefer - Organic Letters, 2011 - ACS Publications
E Racine, F Monnier, JP Vors, M Taillefer
Organic Letters, 2011•ACS PublicationsThe N-arylation of aromatic and aliphatic secondary acyclic amides, known to be poor
nucleophiles, has been accomplished using a simple and cheap copper catalytic system.
The corresponding tertiary acyclic amides, which can be found in numerous biologically
active compounds, have been obtained in good to excellent yields.
nucleophiles, has been accomplished using a simple and cheap copper catalytic system.
The corresponding tertiary acyclic amides, which can be found in numerous biologically
active compounds, have been obtained in good to excellent yields.
The N-arylation of aromatic and aliphatic secondary acyclic amides, known to be poor nucleophiles, has been accomplished using a simple and cheap copper catalytic system. The corresponding tertiary acyclic amides, which can be found in numerous biologically active compounds, have been obtained in good to excellent yields.
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