A unique non-interpenetrated open-framework chalcogenide with a large cavity
M Luo, H Yang, W Wang, C Xue, T Wu - Dalton Transactions, 2018 - pubs.rsc.org
M Luo, H Yang, W Wang, C Xue, T Wu
Dalton Transactions, 2018•pubs.rsc.org… The synthesis of a non-interpenetrated COFMC built on a large-sized Tn cluster but with
a large cavity still remains a big challenge. … In this work, using the versatile template of
TMDP, we demonstrated a unique non-interpenetrated COFMC in the Fe–In–S domain (denoted
as OCF-89, OCF stands for organically directed chalcogenide framework) built on the large
sized T4-FeInS (Fe 4 In 16 S 35 ) cluster. Of significant importance, together with the non-interpenetrated
feature, the framework reported here also has a high extra-framework volume of 70.5%, the …
a large cavity still remains a big challenge. … In this work, using the versatile template of
TMDP, we demonstrated a unique non-interpenetrated COFMC in the Fe–In–S domain (denoted
as OCF-89, OCF stands for organically directed chalcogenide framework) built on the large
sized T4-FeInS (Fe 4 In 16 S 35 ) cluster. Of significant importance, together with the non-interpenetrated
feature, the framework reported here also has a high extra-framework volume of 70.5%, the …
Reported here is a unique non-interpenetrated open-framework metal chalcogenide built on a supertetrahedral [Fe4In16S35]14− cluster. The non-interpenetrated feature accompanied with the relatively large-sized cluster leads to a high extra-framework volume.
The Royal Society of Chemistry