ALD of metal-containing films using cyclopentadienyl compounds

ST Barry, YAM Wasslen, AH Rahtu - US Patent 8,795,771, 2014 - Google Patents
Atomic layer deposition (ALD) type processes for producing metal containing thin films
comprise feeding into a reaction space vapor phase pulses of metal containing cyclopentadi
enyl precursors as a metal source material. In preferred embodiments the metal containing
cyclopentadienyl reactant comprises a metal atom that is not directly bonded to an oxygen or
halide atom. In other embodiments the metal atom is bonded to a cyclopentadienyl
compound and separately bonded to at least one ligand via a nitrogenatom. In still other …

ALD of metal-containing films using cyclopentadienyl compounds

ST Barry, YAM Wasslen, AH Rahtu - US Patent 9,670,582, 2017 - Google Patents
Atomic layer deposition (ALD) type processes for producing metal containing thin films
comprise feeding into a reaction space vapor phase pulses of metal containing
cyclopentadienyl precursors as a metal source material. In preferred embodiments the metal
containing cyclopentadienyl reactant comprises a metal atom that is not directly bonded to
an oxygen or halide atom. In other embodiments the metal atom is bonded to a
cyclopentadienyl compound and separately bonded to at least one ligand via a nitrogen …
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