Ambiguous electrocatalytic CO 2 reduction behaviour of a nickel bis (aldimino) pyridine pincer complex
R Narayanan, M McKinnon, BR Reed, KT Ngo… - Dalton …, 2016 - pubs.rsc.org
Dalton Transactions, 2016•pubs.rsc.org
The electrochemical properties of two Ni (NNN) X2 pincer complexes are reported where X=
Cl or Br and NNN is N, N′-(2, 6-diisopropylphenyl) bis-aldiminopyridine. Cyclic
voltammetry under 1 atm of CO2 suggests electrocatalytic CO2 reduction activity, however,
bulk electrolysis shows a poor Faradaic efficiency for CO evolution with a high Faradaic
yield for H2 evolution.
Cl or Br and NNN is N, N′-(2, 6-diisopropylphenyl) bis-aldiminopyridine. Cyclic
voltammetry under 1 atm of CO2 suggests electrocatalytic CO2 reduction activity, however,
bulk electrolysis shows a poor Faradaic efficiency for CO evolution with a high Faradaic
yield for H2 evolution.
The electrochemical properties of two Ni(NNN)X2 pincer complexes are reported where X = Cl or Br and NNN is N,N′-(2,6-diisopropylphenyl)bis-aldiminopyridine. Cyclic voltammetry under 1 atm of CO2 suggests electrocatalytic CO2 reduction activity, however, bulk electrolysis shows a poor Faradaic efficiency for CO evolution with a high Faradaic yield for H2 evolution.
The Royal Society of Chemistry以上显示的是最相近的搜索结果。 查看全部搜索结果